Co-substituted ATS-type molecular sieves and films for cyclohexane oxidation

作     者：WANG XiaoHui LI Jian WANG YanJi ZHANG BaoQuan LIU XiuFeng 

作者机构：State Key Laboratory of Chemical Engineering and School of Chemical Engineering and Technology Tianjin University Tianjin 300072 China Key Laboratory of Green Chemical Technology & High Efficient Energy Saving of Hebei Province Hebei University of Technology Tianjin 300130 China 

出 版 物：《Chinese Science Bulletin》 (中国科学通报)

年 卷 期：2010年第55卷第36期

页      面：4112-4115页

核心收录：

学科分类：090502[农学-动物营养与饲料科学] 081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 0905[农学-畜牧学] 09[农学] 

基　　金：supported by the National Natural Science Foundation of China (20636030  20776100 and 20776108) 

主　　题：环己烷氧化 兴奋剂 胺类 苯丙 氧化膜 分子筛 剂型 合作 

摘      要：Pure CoAPO-36 crystal grains were synthesized by hydrothermal reaction. Porous α-Al2O3, stainless steel and K2Ti6O13 supported CoAPO-36 films were fabricated using in situ crystallization for the first time. SEM images and XRD measurements demonstrate that a continuous CoAPO-36 film was obtained on the K2Ti6O13 substrate. Diffuse reflectance UV-Vis spectra indicate that Co2+ has been incorporated into the ATS framework. Both CoAPO-36 crystal grains and the K2Ti6O13 supported CoAPO-36 film exhibit satisfactory catalytic activities for the oxidation of cyclohexane.