Continuous flow synthesis of porous materials

作     者：Yu Xin Sheng Peng Junxing Chen Zujin Yang Jianyong Zhang Yu Xin;Sheng Peng;Junxing Chen;Zujin Yang;Jianyong Zhang

作者机构：MOE Laboratory of Polymeric Composite and Functional MaterialsSchool of Materials Science and EngineeringSun Yat-sen UniversityGuangzhou 510275China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2020年第31卷第6期

页      面：1448-1461页

核心收录：

学科分类：07[理学] 070205[理学-凝聚态物理] 0703[理学-化学] 0702[理学-物理学] 

基　　金：the National Natural Science Foundation of China(NSFC,No.51573216) the NSF of Guangdong Province for financial support。 

主　　题：Porous materials Continuous flow Metal-organic frameworks Zeolites Covalent-organic frameworks 

摘      要：Porous materials play an important role in chemical catalysis,separation and other industrial applications.High-efficiency preparation of porous materials has become an active research area.Conventional synthesis of porous materials has been dominated by one-pot solution processing conditions carried out by bulk mixing under conventional electric heating via hydrothermal,solvothermal or ionothermal reactions where high temperatures and pressures are the standard.Continuous flow synthesis has many key advantages in terms of efficient mass and heat transfer,precise control of residence times,improved opportunities for automation and feedback control of synthesis,scaling-up reactions and improved safety parameters compared to above mentioned conventional batch scale synthetic methods.In this review,continuous flow synthesis of various crystalline porous materials such as metal-organic frameworks(MOFs),covalent-organic frameworks(COFs),porous organic cages and zeolites is discussed.Combination of microfluidic methods with other techniques are also shown including various heating ways and various methods of substrate adding.