Preparation and catalytic properties of ZrO_2-Al_2O_3 composite oxide supported nickel catalysts for methane reforming with carbon dioxide

作     者：HAOZheng-ping HUChun JIANGZheng G.Q.LU 

作者机构：ResearchCenterforEeo-EnvironmentalSciencesChineseAcademyofSciencesBeijing100085China. DepartmentofChemicalEngineeringUniversityofQueenslandSt.LuciaQLD4072Australia 

出 版 物：《Journal of Environmental Sciences》 (环境科学学报（英文版）)

年 卷 期：2004年第16卷第2期

页      面：316-320页

核心收录：

学科分类：0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：TheNationalNaturalScienceFoundationofChina(No.50 78094) andChina 863High TechProgram (No .2 0 0 1AA32 4 0 50 ) 

主　　题：oxides catalytic properties methane reforming carbon deposition 

摘      要：ZrO 2-Al 2O 3 composite oxides and supported Ni catalysts were prepared, and characterized by N 2 adsorption /desorption, X-ray diffraction(XRD) an d X-ray photoelectron spectroscopy(XPS) techniques. The catalytic performance and carbon deposition was also investigated. This mesoporous composite oxide is shown to be a promising catalyst support. An increase in the catalytic activity and stability of methane and carbon dioxide reforming reaction was resulted from the zirconia addition, especially at 5wt% ZrO 2 content. The Ni catalyst supported ZrO 2-Al 2O 3 has a strong resistance to sintering and the carbon deposition in a relatively long-term reaction.