Synthesis and Crystal Structure of [Cis-1,10phenanthroline-palladium(Ⅱ)(THF)_2]dinitrate (THF = Tetrahydrofuran)

作     者：HUANG Hui YU Shu-Yan② (State Key Laboratory of Polymer Physics and Chemistry, Joint Laboratory of Polymer Science and Materials, Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080, China) 

作者机构：Institute of Chemistry The Chinese Academy of Sciences State Key Laborator6y of Polymer Physics and Chemistry Joint Laboratory of Polymer Science and Materials CAS 北京 100080 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2003年第22卷第5期

页      面：547-549页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：We thank NNSFC (No. 90206013) foundation for the financial support of this research 

主　　题：crystal structure Pd(Ⅱ) complex 1,10-phenanthroline 

摘      要：A mononuclear complex, cis-1,10-phenanthroline-palladium(Ⅱ)(THF)2]dinitrate (THF = tetrahydrofuran) [Pd(C10H8N2)(C4H8O)2](NO3)2 1, has been prepared and structurally characterized by single-crystal X-ray diffraction. The crystal belongs to monoclinic system, space group P21/c with a = 7.881(1), b = 27.371(3), c = 10.178(1) ? ?= 103.313(3)? V = 2136.5(4) 3, Mr = 554.83, Dc = 1.725 g/cm3, Z = 4, F(000) = 1128 and (MoK) = 0.926 mm-1. The structure was refined to R = 0.0678 and wR = 0.1651 for 1687 observed reflections with I 2(I). It is revealed that the central Pd(Ⅱ) ion in the title complex is bonded to two THF and two phenanthroline molecules in a cis-configuration to form the coordination geometry, deviating slightly from the square plane.