Studies on sulfinatodehalogenation ⅫⅠ.Synthesis of 2-perfluoroalkyl-2-deoxy-D-glucose,mono- and poly-O-polyfluoroalkylated-D-glucoses

作     者：HUANG,Wei-Yuan XIE,Yuan Shanghai Institute of Organic Chemistry,Academia Sinica,Shanghai 200032 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：1991年第9卷第4期

页      面：351-359页

核心收录：

学科分类：07[理学] 0703[理学-化学] 

基　　金：This work was partially supported by the National Natural Science Foundation of China 

主　　题：Synthesis of 2-perfluoroalkyl-2-deoxy-D-glucose,mono and poly-O-polyfluoroalkylated-D-glucoses Studies on sulfinatodehalogenation 

摘      要：The reaction of perfluoroalkyl iodide or perfluoroalkyl bromide with sulfite radical anion (SO_3^-)generated from sodium bisulfite/potassium ferricyanide in water/DMF at 70—75°C gave the corresponding perfluoroalkanesulfinate ia good ***,it was shown that the reagent system can also initiate the addition of perfluoroalkyl iodide to olefins or alkynes at 50—65℃.