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FeCo-based hybrid MOF derived active species for effective oxygen evolution

FeCo-based hybrid MOF derived active species for effective oxygen evolution

作     者:Yuanjun Liu Cheng Wang Suxiao Ju Mo Li Aihua Yuan Guoxing Zhu Yuanjun Liu;Cheng Wang;Suxiao Ju;Mo Li;Aihua Yuan;Guoxing Zhu

作者机构:School of Environmental and Chemical EngineeringJiangsu University of Science and Technology Marine Equipment and Technology InstituteJiangsu University of Science and Technology School of Chemistry and Chemical EngineeringJiangsu University 

出 版 物:《Progress in Natural Science:Materials International》 (自然科学进展·国际材料(英文))

年 卷 期:2020年第30卷第2期

页      面:185-191页

核心收录:

学科分类:081702[工学-化学工艺] 081704[工学-应用化学] 07[理学] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 070304[理学-物理化学(含∶化学物理)] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 0702[理学-物理学] 

基  金:National Natural Science Foundation of China (No.21776115) Jiangsu Natural Science Foundation (No. BK20161343) Six talent peaks project in Jiangsu Province (XCL-2018017) Foundation from Marine Equipment and Technology Institute for Jiangsu University of Science and Technology,China (HZ20190004) 

主  题:Metal-organic frameworks Oxygen evolution Cobalt Iron Electrocatalysts Water oxidation 

摘      要:Metal-organic frameworks(MOFs) have been regarded as promising catalyst materials due to the richness of coordinately unsaturated metal sites on the surface,which can act as catalytic active *** this study,a hybrid MOF material composed of Fe-based MOF and Co-based MOF was prepared with the involvement of graphene oxide nanosheets as *** was demonstrated that the hybrid MOF materials showed much higher electro-catalytic activity towards oxygen evolution than the single-phase *** drive current density of 10 mA cm;,the hybrid CoFe-based MOF only needed an over potential of 290 mV in 1 M *** catalytic activity could sustain for a longer time with only slight current density *** oxygen evolution operation,the MOF catalyst evolved into catalytic active species but kept well the microscale sheet-like *** is thus believed that this study will provide an avenue for the development of advanced electrocatalysts.

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