Synthesis of Pt nanocatalysts for selective hydrogenation of ortho-halogenated nitrobenzene

作     者：Ruigang Xie Xueqin Cao Yue Pan Hongwei Gu 

作者机构：Key Laboratory of Organic Synthesis of Jiangsu Province College of Chemistry Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology Soochow University 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2015年第58卷第6期

页      面：1051-1055页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：financially supported by the National Natural Science Foundation of China(21373006,51402203) the Natural Science Foundation of Jiangsu Province for Young Scholars(BK20140326) the Natural Science Foundation of Jiangsu Higher Education Institutions(14KJB430021) the Priority Academic Program Development of Jiangsu Higher Education Institutions 

主　　题：卤代硝基苯 纳米催化剂 选择性氢化 合成 Fe(CO)5 铂 纳米颗粒 反应条件 

摘      要：Monodisperse Pt nanoparticles(NPs) were prepared by reduction of platinum acetylacetonate in octadecene with the presence of Fe(CO)5. The synthesized nanocatalysts presented high activity and selectively for hydrogenation of ortho-halogenated nitrobenzene to the corresponding ortho-halogenated aniline under mild reaction conditions.