[Bmim]OAc Catalyzed Michael Addition of Active Methylene to α,β-Unsaturated Carboxylic Esters and Nitriles

作     者：YANG Yu WANG Li-bing ZHANG Zhan LI Cai-meng FU Xian-lei GAO Guo-hua 

作者机构：Shanghai Key Laboratory of Green Chemistry and Chemical Processes Department of Chemistry East China Normal University Shanghai 200062 P R. China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2010年第26卷第4期

页      面：554-557页

核心收录：

学科分类：081702[工学-化学工艺] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Supported by the National Natural Science Foundation of China(Nos.20533010 and 20873041) Shanghai Leading Academic Discipline Project,China(No.B409) 

主　　题：Michael addition [Bmim]OAc Bis-addition Mild reaction condition 

摘      要：Michael addition of active methylene compounds to α,β-unsaturated carboxylic esters and nitriles was effectively catalyzed by a basic ionic liquid, 1-butyl-3-methylimidazolium acetate（[Bmim]OAc）. The his-addition products were selectively obtained in high yields under mild reaction conditions.