Synthesis and Crystal Structure of a Novel Zincophosphite Containing Two-dimensional Inorganic-organic Network

作     者：杨雅莉 李牛 项寿鹤 

作者机构：Institute of New Catalytic Material Science College of Chemistry Nankai University 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2004年第22卷第4期

页      面：344-347页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：ChinaPetroleum&ChemicalCorporation(No.X501024)andtheNationalNaturalScienceFoundationofChina(No.20233030) 

主　　题：zincophosphite hydrothermal synthesis two-dimensional network 

摘      要：A novel 1,6-hexamethylenediamine-zincophosphite has been synthesized hydrothermally. Its single-crystal structure refinement has shown the zincophosphite with the composition NH3+ (CH2)(6) NH3+ [Zn(HPO3)(2)](2-), M-r = 343.55. It crystallizes in monoclinic, space group C2/c (No.15), a=2.2391 nm, b=0.8695 nm, c=0.7919 nm, beta = 101.062(6)degrees, V= 1.513 nm(3), D-c=1.508 kg/m(3), Z=4, F(000)=712,mu= 1.849 mm(-1), R-1=0.0416, wR(2)=0.1023. This phase exhibits infinite inorganic chains of vertex-linked ZnO4 and HPO3. Via the electrostatic attraction, 1,6-hexainethylenediamine cations and inorganic chains construct a novel interesting two-dimensional inorganic-organic network.