A New Tin Graphite Intercalation Compound for Lithium Ion Batteries

作     者：XIE Hai-ming YAN Xue-dong YU Hai-ying ZHANG Ling-yun YANG Gui-ling XU Yang WANG Rong-shun 

作者机构：Department of Chemistry Northeast Normal University Changchun 130024 P. R. China Department of Chemistry Inner Mongolia University for NationalitiesTongliao 028043 P. R. China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2006年第22卷第5期

页      面：639-642页

核心收录：

学科分类：0808[工学-电气工程] 08[工学] 

基　　金：Supported by the Fund of the Science and Technology Department of Jilin Province  China(No. 2005415) 

主　　题：Lithium ion battery Anode material Sn-GIC 

摘      要：A new composite material was fabricated by intercalating tin nanoparticles into graphite. The tin graphite intercalation compound（Sn-GIC） was prepared by the interactions of tin tetrachloride with KC8 （K-GIC） in tetrahydrofuran （THF）. As the anode of lithium ion batteries, Sn-GIC presents a steady reversible capacity（363 mA·h/g） and a good cycling performance in comparison with Sn and SnO2, it suggests that the association of tin with graphite not only improves the reversible capacities, but also prevents the volume changes resulted from lithium insertion and extraction with tin during a charge-discharge process.