Synthesis and Catalytic Study of Ruthenium Carbene Catalyst Containing a Zn-Porphyrin Ligand

作     者：Ying Xu Huizhu Zhang Xinyuan Wang Guiyan Liu 

作者机构：Tianjin Key Laboratory of Structure and Performance for Functional MoleculesKey Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry(Tianjin Normal University)Ministry of Education College of ChemistryTianjin Normal UniversityTianjin300387China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2015年第33卷第12期

页      面：1393-1397页

核心收录：

学科分类：081702[工学-化学工艺] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：This work was supported by the National Natural Science Foundation of China (grant No. 21102102) 

主　　题：olefin metathesis ruthenium carbene catalyst Zn-porphyrin 

摘      要：A ruthenium carbene complex containing a Zn-porphyrin ligand has been developed. The complex was charac- terized by 1H NMR, IR, HRMS and elemental analysis. The catalytic activity of the ruthenium carbene complex for olefin metathesis reactions was also investigated. The complex exhibited excellent performance for both ring-closing and cross metathesis reactions at 35 ℃.