Synthesis, Characterization and Solvatochromism Investigation of Mixed Ligand Chelate Copper（Ⅱ） Complexes with Acetyleacetonate and Three Diamine Ligands

作     者：Golchoubian Hamid Afshar Zahra Mohseni Moayyedi Golasa Bruno Giuseppe Rudbari Hadi Amiri 

作者机构：Department of Chemistry University of Mazandaran Babol-sar Postal Code 47416-95447 Iran Dipartimento di Chimica Inorganica Vill. S. Agata Salita Sperone 31 Universith di Messina 98166 Messina Italy 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2012年第30卷第8期

页      面：1873-1880页

核心收录：

学科分类：081702[工学-化学工艺] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：the financial support of University of Mazandaran of the Islamic Republic of Iran 

主　　题：mixed-chelate solvatochromism X-ray crystal structure SMLR method diamine copper(Ⅱ) tetra-phenylborate 

摘      要：The syntheses of three mixed ligand chelate copper（II） complexes of the type [Cu（L）（acac）（H2O）]BPh4 where acac=acetyleacetonate; L=N,N-dimethyl,N′-benzylethane-1,2-diamine （L1）, N,N-dimethyl, N′-2-methylbenzylethane-1,2-diamine （L2） or N,N-dimethyl,N′-2-chlorobenzylethane-1,2-diamine （L3） are reported and characterized by elemental analyses, spectroscopic and molar conductance measurements. The X-ray structure of complex 1 shows that the central copper atom is placed in a distorted square pyramidal geometry made by acac and diamine chelate in the base and a H2O molecule on the apex. The prepared complexes are fairly soluble in a large number of organic solvents and show positive solvatochromism. Calculations of SMLR （stepwise multiple linear regression） method was utilized to find the best model explaining the observed solvatochromic behavior and showed that among different solvent parameters, donor number （DN） is a dominant factor responsible for the shift in the d-d absorption band of the complexes to the lower wavenumber with increasing its values. The importance of substituent effect in diamine ligand on the spectral and SMLR measurements is also discussed.