Catalytic Hydrogenation of Diacetyl Monoxime to Tetramethylpyrazine with the Soluble Transition Metal Catalysts

作     者：Xiang Yu WANG Xiao Ming ZHENG Zhao Yin HOU (Institute of Catalysis, Zhejiang University (Xixi campus), Hangzhou 310028) (Department of Chemistry, Zhengzhou University, Zhengzhou 450052) 

作者机构：Institute of Catalysis Zhejiang University (Xixi Campus) Hangzhou 310028 China Department of Chemistry Zhengzhou University Zhengzhou 450052 China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：1999年第10卷第8期

页      面：701-704页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

主　　题：diacetyl monoxime catalytic hydrogenation tetramethylpyrazine 

摘      要：Catalytic hydrogenation of diacetyl monoxime to tetramethylpyrazine, by the homogeneous catalysts generated in situ from some transition metal chlorides with triphenylphosphine in ethanol under H-2 pressure of 0.6 similar to 4.6 MPa at 100 similar to 150 degrees C, has been studied. The optimum H-2 partial pressure was observed at about 1.3 MPa. The maximum conversion of diacetyl monoxime and yield of tetramethylpyrazine were 97% and 90%, respectively.