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Synthesis and electrochemical properties of Li_(1-x)V_xCr_yFe_(1-x)PO_4/C as a cathode material

Synthesis and electrochemical properties of Li_(1-x)V_xCr_yFe_(1-x)PO_4/C as a cathode material

作     者:Shi Tao Song Pei Hua Ma Shi You Li Xiao Chuan Deng Chun Yan Yan 

作者机构:Qinghai Institute of Salt Lakes Chinese Academy of Sciences Xining 810008 China Graduate School of the Chinese Academy of Sciences Beijing 100039 China 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:2008年第19卷第3期

页      面:337-341页

核心收录:

学科分类:07[理学] 0703[理学-化学] 

基  金:Science and Technology Foundation of Qinghai Province, (2006-G-168) Key Technologies Research and Development Program, (2004BA602B-01) 

主  题:Li1-xVxCryFe1-yPO4/C Cathode material Ion doping 

摘      要:Composites Li1-xVxCryFe1-yPO4/C(x=0.01, 0.02; y = 0.01, 0.02) were synthesized by solid-state reaction method. The influence of the content of doping vanadium and chromium on the structure of Li1-xVxCryFe1-yPO4/C was investigated by XRD, while the morphology of powders was observed by SEM. The investigation of the electrochemical performances showed that the Li0.99V0.01Cr0.02Fe0.98PO4/C material has a higher capacity. At 0.1 C discharging rate, it is capable of delivering reversible specific capacity of 163.8 mAh/g with fairly stable cycleability.

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