Nickel-Catalyzed Reductive Coupling of Aldehydes with Alkynes Mediated by Alcohol
NickelCatalyzed 与炔属羟的醛的减少的联合由白酒 <sup></sup> 调停了作者机构:State Key Laboratory and Institute of Elemento-Organic ChemistryNankai UniversityTianjin 300071China
出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))
年 卷 期:2020年第38卷第5期
页 面:489-493页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金:We thank the National Natural Science Foundation of China(Nos.21672107,91856104 and 21871145) "the Fundamental Research Funds for the Central Universities",Nankai University(No.63191601)for financial support
摘 要:A nickel-catalyzed reductive coupling of aldehydes with aikynes using 1-phenylethanol as reducing agent has been *** key achievement of this work is that we demonstrate environmentally benign 1-phenylethanol can serve as a viable alternative reducing agent to Et3B,ZnEt2 and R3SiH for the nickel-catalyzed reductive coupling reaction of aldehyde and alkynes.