Interaction of ciprofloxacin hydrochloride with sodium dodecyl sulfate in aqueous/electrolytes solution at different temperatures and compositions

作     者：Sk.Md.Ali Ahsan Md.Ruhul Amin Shamim Mahbub Mohammad Robel Molla Shahina Aktar Malik Abdul Rub Md.Anamul Hoque Muhammad Nadeem Arshad Mohammed Abdullah Khan Sk.Md.Ali Ahsan;Md.Ruhul Amin;Shamim Mahbub;Mohammad Robel Molla;Shahina Aktar;Malik Abdul Rub;Md.Anamul Hoque;Muhammad Nadeem Arshad;Mohammed Abdullah Khan

作者机构：Department of ChemistryJahangirnagar UniversitySavarDhaka 1342Bangladesh Chemistry DepartmentFaculty of ScienceKing Abdulaziz UniversityJeddah-21589Saudi Arabia Center of Excellence for Advanced Materials ResearchKing Abdulaziz UniversityJeddah-21589Saudi Arabia 

出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报（英文版）)

年 卷 期：2020年第28卷第1期

页      面：216-223页

核心收录：

学科分类：1007[医学-药学(可授医学、理学学位)] 081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 10[医学] 

基　　金：funded by the Deanship of Scientific Research(DSR) King Abdulaziz University,Jeddah,under grant No.(D-403-130-1441) 

主　　题：Ciprofloxacin hydrochloride Sodium dodecyl sulfate Critical micelle concentration Thermodynamic indices Hydrophobic effect 

摘      要：Interactions of ciprofloxacin hydrochloride(CPFH)with sodium dodecyl sulfate(SDS)were investigated by conductivity measurement in H2O/electrolyte solutions(NaCl,Na2SO4&Na3PO4)over 298.15–318.15 K temperature range(with 5 K interval)considering the human body *** all cases,two critical micelle concentrations(c*)were observed which are increased in the presence of drug and decreased in the presence of salts enunciating the presence of interaction amongst the studied ***(CPFH+SDS)system in the presence of salt,the c*values at 303.15 K and I=0.50 mmol·kg^-1 followed the order:CNaClCNa2SO4***ΔG1,m0 andΔG2,m0values are found to be negative for all systems that show that the micellization process is thermodynamically ***(CPFH+SDS)system in water,theΔHm0&ΔSm0 values reveal that the micellization processes is both entropy dominated in almost all *** the occurrence of electrolytes,ΔHm0 andΔSm0 values indicate that micellization processes are both entropy&enthalpy restricted at upper temperature but it becomes totally entropy dependent at higher *** higher positiveΔSm0 values indicate the enhanced hydrophobic interaction in presence of *** enthalpy-entropy compensation was determined from the linear relationship betweenΔHm0 andΔSm0 values in every *** transfer energies as well as compensation temperature and intrinsic enthalpy were also evaluated and the behaviors were comparable to other biological system.