Adsorption characteristics of ciprofloxacin onto g-MoS2 coated biochar nanocomposites
作者机构:Department of Environmental ScienceZhejiang UniversityHangzhou 310058China Zhejiang Provincial Key Laboratory of Organic Pollution Process and ControlHangzhou 310058China
出 版 物:《Frontiers of Environmental Science & Engineering》 (环境科学与工程前沿(英文))
年 卷 期:2020年第14卷第3期
页 面:49-58页
核心收录:
学科分类:12[管理学] 1204[管理学-公共管理] 082803[工学-农业生物环境与能源工程] 07[理学] 070205[理学-凝聚态物理] 08[工学] 0828[工学-农业工程] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 120405[管理学-土地资源管理] 0702[理学-物理学]
基 金:This work was supported by the National Key Research and Development Program of China(No.2018YFC1800704) the National Natural Science Foundation of China(No.21577124)
主 题:Adsorption Ciprofloxacin g-MoS2 nanosheets Biochar Soil remediation
摘 要:The g-MoS2 coated biochar(g-MoS2-BC)composites were synthesized by coating original biochar with g-MoS2 nanosheets at 300℃(BC300)/700℃(BC700).The adsorption properties of the g-MoS2-BC composites for ciprofloxacin(CIP)were investigated with an aim to exploit its high efficiency toward soil *** specific surface area and the pore structures of biochar coated g-MoS2 nanosheets were significantly *** g-MoS2-BC composites provided more n electrons,which was favorable in enhancing the n-n electron donor-acceptor(EDA)interactions between CIP and *** a result,the g-MoS2-BC composites showed faster adsorption rate and greater adsorption capacity for CIP than the original *** coated g-MoS2 nanosheets contributed more to CIP adsorption on the g-MoS2-BC composites due to their greater CIP adsorption capacity than the original ***,the synergistic effect was observed for CIP adsorption on g-MoS2-BC700,and suppression effect on *** addition,the adsorption of CIP onto g-MoS2-BC composites also exhibited strong dependence on the solution pH,since it can affect both the adsorbent surface charge and the speciation of *** was reasonably suggested that the mechanisms of CIP adsoiption on g-MoS2-BC composites involved pore-filling effects,k-k EDA interaction,electrostatic interaction,and ion exchange *** results are useful for the modification of biochar in exploiting the novel amendment for contaminated soils.