A granular adsorbent-supported Fe/Ni nanoparticles activating persulfate system for simultaneous adsorption and degradation of ciprofloxacin

作     者：Jiwei Liu Yufeng Du Wuyang Sun Quanchao Chang Changsheng Peng Jiwei Liu;Yufeng Du;Wuyang Sun;Quanchao Chang;Changsheng Peng

作者机构：Key Lab of Marine Environmental Science and EcologyMinistry of EducationOcean University of ChinaQingdao 266100China School of EnvironmentTsinghua UniversityBeijing 100084China School of Environmental and Chemical EngineeringZhaoqing UniversityZhaoqing 526061China 

出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报（英文版）)

年 卷 期：2020年第28卷第4期

页      面：1077-1084页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 

基　　金：the support of the State Key Laboratory of Environmental Criteria and Risk Assessment(SKLECRA2013FP12) the Shandong Province Key Research and Development Program(2016GSF115040) 

主　　题：Fe/Ni@PGA Ciprofloxacin Persulfate Sulfate radical Oxidation Adsorption 

摘      要：In this work,Fe/Ni nanoparticles were produced through Fe(II)and Ni(II)reduction by NaBH4 and they were stabilized by a kind of prepared granular adsorbent(Fe/Ni@PGA).Fe/Ni@PGA as an environment-friendly activator was used to activate persulfate(PS)for the removal of ciprofloxacin from aqueous ***/Ni@PGA was systematically characterized via Brunauer-Emmett-Teller(BET)method,X-ray diffraction(XRD),scanning electron microscopy(SEM),and Fourier transform infrared spectroscopy(FTIR).The effects of PS concentration,initial solution pH,Fe/Ni@PGA dosage,initial ciprofloxacin concentration,reaction temperature,anions,and natural organic matters on the removal of ciprofloxacin by Fe/Ni@PGA/PS were *** removal efficiency of ciprofloxacin by Fe/Ni@PGA/PS was 93.24%under an initial pH of 3.0,PS concentration of 10 mM,Fe/Ni@PGA dosage of 0.1 g,and reaction temperature of 30℃.Fe/Ni@PGA could still exhibit high catalytic activity after nine cycles of *** removal mechanisms for ciprofloxacin by the Fe/Ni@PGA/PS system were *** summary,the Fe/Ni@PGA/PS system could be applied as a promising technology for ciprofloxacin removal.