Study of Mechanisms of CO and NO2O xidation on Zn–CNT(6,0) and Zn–BNNT(6,0),Mn–B38N38 and Mn–C76

作     者：ZENG Zhi-Wen LI Xiang ZHANG Fu-Xing NAJAFI Meysam 曾智文;李翔;张复兴;NAJAFI Meysam

作者机构：Department of Basic CoursesHunan Polytechnic of Environment and BiologyHengyang 421005China Department of Medical and TechnicalHunan Polytechnic of Environment and BiologyHengyang 421005China Department of Chemistry and Material ScienceHengyang Normal UniversityHengyang 421008China Medical Biology Research CenterHealth Technology InstituteKermanshah University of Medical SciencesKermanshah 67149-67346Iran 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2020年第39卷第1期

页      面：41-47,2页

核心收录：

学科分类：081705[工学-工业催化] 07[理学] 070205[理学-凝聚态物理] 08[工学] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0702[理学-物理学] 

基　　金：The Innovation Platform Open Foundation for Colleges and Universities of Hunan Province–Synthesis Structure and Performance of Metal Ions Fluorescent Probes Based on Complex ones(No.GN19K02) 

主　　题：NO2 CO2 catalyst mechanism nano Mn and Zn 

摘      要：The abilities and performances of Mn–C76,Mn–B38N38,Zn–CNT(6,0)and Zn–BNNT(6,0)to the oxidation of NO2 and CO are *** oxidation reactions of NO2 and CO through the Langmuir-Hinshelwood(LH)and Eley-Rideal(ER)mechanisms by theoretical methods are *** most stable intermediates of oxidation reactions of NO2 and CO on Mn–C76,Mn–B38N38,Zn–CNT(6,0)and Zn–BNNT(6,0)are obtained from thermodynamics view *** the LH pathway,Mn–C76,Mn–B38N38,Zn–CNT(6,0)and Zn–BNNT(6,0)catalysts are deactivated via the second NO2 and CO *** the ER pathway,the second NO3 and CO2 molecules are ***,the Mn–C76,Mn–B38N38,Zn–CNT(6,0)and Zn–BNNT(6,0)are proposed to oxidize NO2 and CO molecules with high performances at room temperature.