液晶CPBOB吸附的STM研究
Scanning Tunneling Microscope (STM) Studies of Liquid Crystals of CPBOB作者机构:辽宁师范大学化学系大连116022 中国科学院化学研究所北京100080
出 版 物:《物理化学学报》 (Acta Physico-Chimica Sinica)
年 卷 期:1996年第12卷第10期
页 面:957-960页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 070205[理学-凝聚态物理] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 0702[理学-物理学]
摘 要:The adsorption structures of 4-cyanophenyl 4-butoxy benzoate(CPBOB) on graphite are studied by Scanning Tunneling Microscope(STM) at room temperature from the mixture of two different liquid crystals. STM images of CPBOB molecules are visualized for the first time with a near-atomic resolution. The adsorption structures are also investigated by molecular dynamical calculation. The STM images of CPBOB are stable in the period of 12 hours. These results indicate that liquid crystals of higher melting point on the surface of graphite can be studied by STM at the room temperature and the CPBOB mnolecules in a unit are orientated in the way of head to head.