Layered carbon-based pseudocapacitive materials for lithium/sodium-ion capacitor with high energy-power densities and long cycle life
Layered carbon-based pseudocapacitive materials for lithium/sodium-ion capacitor with high energy-power densities and long cycle life作者机构:State Key Laboratory of New Ceramics and Fine ProcessingSchool of Materials Science and EngineeringTsinghua University Key Laboratory of Advanced Materials (MOE)School of Materials Science and EngineeringTsinghua University
出 版 物:《Progress in Natural Science:Materials International》 (自然科学进展·国际材料(英文))
年 卷 期:2020年第30卷第1期
页 面:20-27页
核心收录:
学科分类:080801[工学-电机与电器] 0808[工学-电气工程] 08[工学]
基 金:the financial support from the National Natural Science Foundation of China (Grant No.51722207)
主 题:Sodium/lithium-ion capacitors High energy-power density Pseudocapacitive electrodes Layered materials
摘 要:Hybrid ion capacitors that combined high-power density of supercapacitor and high-energy density of battery are drawing attention to insufficient power densities of currently-used lithium-ion batteries(LIBs).Two kinds of layered carbon-based pseudocapacitive materials were used as both anode and cathode for lithium/sodium ion capacitors(LICs/NICs) with balanced energy/power ***-assembled NIC and LIC could deliver the energy densities of 125.7 Wh kg;and 119.6 Wh kg;at the power density of 7941.2 W kg;and 8823.5 W kg;,*** electrochemical properties of NICs were better than that of LICs when the current density was below 4 A g;although the working voltage of LIC is higher than that of NICs,and the size of Na;is larger than that of Li;.Using an instantaneous potential technique,it is found that the increase of the capacity for anode material in low potential region will effectively enhance the electrochemical performance for the full device.