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Layered carbon-based pseudocapacitive materials for lithium/sodium-ion capacitor with high energy-power densities and long cycle life

Layered carbon-based pseudocapacitive materials for lithium/sodium-ion capacitor with high energy-power densities and long cycle life

作     者:Mingxiang Hu Hongwei Zhang Ruitao Lv Mingxiang Hu;Hongwei Zhang;Ruitao Lv

作者机构:State Key Laboratory of New Ceramics and Fine ProcessingSchool of Materials Science and EngineeringTsinghua University Key Laboratory of Advanced Materials (MOE)School of Materials Science and EngineeringTsinghua University 

出 版 物:《Progress in Natural Science:Materials International》 (自然科学进展·国际材料(英文))

年 卷 期:2020年第30卷第1期

页      面:20-27页

核心收录:

学科分类:080801[工学-电机与电器] 0808[工学-电气工程] 08[工学] 

基  金:the financial support from the National Natural Science Foundation of China (Grant No.51722207) 

主  题:Sodium/lithium-ion capacitors High energy-power density Pseudocapacitive electrodes Layered materials 

摘      要:Hybrid ion capacitors that combined high-power density of supercapacitor and high-energy density of battery are drawing attention to insufficient power densities of currently-used lithium-ion batteries(LIBs).Two kinds of layered carbon-based pseudocapacitive materials were used as both anode and cathode for lithium/sodium ion capacitors(LICs/NICs) with balanced energy/power ***-assembled NIC and LIC could deliver the energy densities of 125.7 Wh kg;and 119.6 Wh kg;at the power density of 7941.2 W kg;and 8823.5 W kg;,*** electrochemical properties of NICs were better than that of LICs when the current density was below 4 A g;although the working voltage of LIC is higher than that of NICs,and the size of Na;is larger than that of Li;.Using an instantaneous potential technique,it is found that the increase of the capacity for anode material in low potential region will effectively enhance the electrochemical performance for the full device.

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