Electrochemical exfoliation of two-dimensional layered black phosphorus and applications

作     者：Le Li Dan Zhang Jianping Deng Yuchun Gou Junfei Fang Le Li;Dan Zhang;Jianping Deng;Yuchun Gou;Junfei Fang

作者机构：Shaanxi Key Laboratory of Industrial AutomationSchool of Mechanical EngineeringShaanxi University of TechnologyHanzhong 723001ShaanxiChina Shaanxi Province Key Laboratory of Catalytic Foundation and ApplicationSchool of Chemistry and Environment ScienceShaanxi University of TechnologyHanzhong 723001ShaanxiChina 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2020年第29卷第10期

页      面：365-374页

核心收录：

学科分类：0808[工学-电气工程] 081704[工学-应用化学] 07[理学] 070205[理学-凝聚态物理] 08[工学] 0820[工学-石油与天然气工程] 0817[工学-化学工程与技术] 0807[工学-动力工程及工程热物理] 080501[工学-材料物理与化学] 0827[工学-核科学与技术] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学] 

基　　金：financially supported by the Youth talent support program of science and technology association of colleges of Shaanxi Province(Grant No.20190609) the Special scientific research plan of education department of Shaanxi province(Grant No.19JK0190 and 19JK0186) the Natural Science Foundation of Shaanxi Province(Grant No.2019JM508) the Open project of Key laboratory of catalytic foundation and application of Shaanxi province(Grant No.SLGPT2019KF01-23) the Opening Foundation of Shaanxi Key Laboratory of Industrial Automation(No.SLGPT2019KF01-10) the School-level project of Shaanxi University of Technology(Grant No.SLGRC03,SLGRC02) 

主　　题：Black phosphorus Electrochemical exfoliation 2D BP sheets Anode exfoliation Cathodic exfoliation 

摘      要：With the discovery of graphene,black phosphorus(BP)has been rediscovered as a two-dimensional(2 D)layered *** its first preparation in 2014,2 D BP has elicited immense interest,and has exhibited excellent properties,such as distinct pleated structures in layers,adjustable direct bandgap,high carrier mobility,moderate on/off ratio,large specific surface area,and various interesting in-layer ***,the realization of these excellent properties depends on the preparation of highquality 2 D BP *** exfoliation methods are typically performed under mild conditions,thus,these methods are convenient,controllable,and can produce high-quality 2 D BP *** review summarizes research progress in BP sheets preparation through anodic,cathodic,and electrolyte exfoliation in recent *** exfoliating methods affect the quality of 2 D BP ***,possible exfoliating mechanisms and the potential applications of different exfoliating methods are summarized and discussed in ***,the shortcomings of existing research on electrochemical exfoliation are presented,and suggestions and prospects for future research on the electrochemical exfoliation of 2 D BP are proposed.