Perpendicular intergrowth ZSM-5 plates with shortened 10-MR pores

作     者：Ensheng Zhan Zhiping Xiong Yan Zhou Mingrun Li Pengfei Wang Weibin Fan Wenjie Shen 展恩胜;熊志平;周燕;李名润;王鹏飞;樊卫斌;申文杰

作者机构：State Key Laboratory of CatalysisDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina State Key Laboratory of Coal ConversionInstitute of Coal ChemistryChinese Academy of SciencesTaiyuan 030001ShanxiChina University of Chinese Academy of SciencesBeijing 100049China 

出 版 物：《Chinese Journal of Catalysis》 (催化学报（英文）)

年 卷 期：2020年第41卷第7期

页      面：1132-1139页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：国家自然科学基金(21773229) 

主　　题：ZSM-5 Plate structure Perpendicular Intergrowth Channel length Hierarchical structure Molecule diffusion 

摘      要：ZSM-5 plates with a perpendicular intergrowth structure was synthesized by using a simple amine as the structure directing agent under hydrothermal conditions,in which the mother plate and the perpendicularly standing plates oriented along the(010)and(100)planes of MFI crystals,*** the crystallization process,the mother plate was initially formed on the surface of the amorphous solid gel,while a set of parallel plates perpendicularly grew on its surface,via a homogeneous nucleation *** mother plate and the perpendicular plates had a similar thickness of 100-200 nm and were characterized by considerably shortened straight and zigzag 10 member ring pores,*** unique intergrowth structure greatly facilitated the diffusion of the reactive molecules in HZSM-5 crystals during methanol conversion to hydrocarbons.