Solid-state NMR for metal-containing zeolites:from active sites to reaction mechanism

作     者：Xingling Zhao Jun Xu Feng Deng Xingling Zhao;Jun Xu;Feng Deng

作者机构：National Center for Magnetic Resonance in WuhanState Key Laboratory of Magnetic Resonance and Atomic and Molecular PhysicsCAS Key Laboratory of Magnetic Resonance in Biological SystemsWuhan Institute of Physics and MathematicsInnovation Academy for Precision Measurement Science and TechnologyChinese Academy of SciencesWuhan 430071China University of Chinese Academy of SciencesBeijing 100049China Wuhan National Laboratory for OptoelectronicsHuazhong University of Science and TechnologyWuhan 430074China 

出 版 物：《Frontiers of Chemical Science and Engineering》 (化学科学与工程前沿（英文版）)

年 卷 期：2020年第14卷第2期

页      面：159-187页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：国家自然科学基金 Key Program for Frontier Science of the Chinese Academy of Sciences 湖北省自然科学基金 

主　　题：metal-containing zeolites solid-state NMR active site host-guest interaction reaction mechanism 

摘      要：Metal-containing zeolite catalysts have found a wide range of applications in heterogeneous *** understand the nature of metal active sites and the reaction mechanism over such catalysts is of great importance for the establishment of structure-activity *** advanced solid-state NMR(SSNMR)spectroscopy is robust in the study of zeolites and zeolite-catalyzed *** this review,we summarize recent developments and applications of SSNMR for exploring the structure and property of active sites in metal-containing ***,detailed information on host-guest interactions in the relevant zeolite catalysis obtained by SSNMR is also ***,we highlight the mechanistic understanding of catalytic reactions on metal-containing zeolites based on the observation of key surface species and active intermediates.