Electrochemical synthesis and characterization of polydiphenylamine

作     者：DONG,Shao-Jun SONG,Fa-Yi LI,Zhuang Laboratory of Electroanalytical Chemistry,Changchun Institute of Applied Chemistry,The Chinese Academy of Sciences,Changchun,Jilin 130022 

作者机构：Laboratory of Electroanalytical Chemistry Changchun Institute of Applied Chemistry The Chinese Academy of Sciences Changchun Jilin 130022 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：1992年第10卷第1期

页      面：10-16页

核心收录：

学科分类：07[理学] 0703[理学-化学] 

基　　金：Work supported by the National Natural Science Foundation of China 

主　　题：Electrochemical synthesis and characterization of polydiphenylamine PDPA 

摘      要：Electrochemical oxidation of diphenylamine(DPA)in acetonitrile solution produced an adhesive conducting polydiphenylamine(PDPA)film on the electrode,which exhibited multiple colour variation in a wide range of *** polymer was characterized by cyclic voltam- merry,FTIR and *** results indicate that the electropolymerization of diphenylamine per- forms via the 4,4＇C—C phenyl-phenyl coupling ***,ESR and conductivity mea- surements for the different states of PDPA show that polydiphenylamine can be reversibly doped and dedoped either chemically or *** is evidenced also that there are paramagnetic species—polarons in PDPA supposed to be the current carrier.