一种镧系-过渡金属二维氰桥配合物[Nd(DMSO)_2(H_2O)_2][Ni(CN)_4]Cl(DMSO=二甲亚砜)的合成和晶体结构(英文)
Synthesis and Crystal Structure of a Cyano-Bridged Lanthanide-Transition-Metal Complex [Nd(DMSO)_2(H_2O)_2][Ni(CN)_4]Cl (DMSO=Dimethylsulfoxide) with Two-dimensional Gridding Molecule Structure作者机构:南开大学化学学院天津300071
出 版 物:《无机化学学报》 (Chinese Journal of Inorganic Chemistry)
年 卷 期:2005年第21卷第7期
页 面:1055-1059页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 070301[理学-无机化学]
主 题:晶体结构 二甲亚砜 过渡金属 complex 配合物 crystal 合成 氰桥 二维 镧系 Nd^3+ space group final with unit data The the was and all are for
摘 要:The cyano-bridged bimetallic complex [Nd(DMSO)2(H2O)2][Ni(CN)4]Cl with two-dimensional gridding molecule structure was synthesized and characterized. In the complex all four cyano groups of unit Ni(CN)42- are bound to Nd3+ ions. The crystal data for the title complex: monoclinic, space group P21/c, a=0.780 0(3) nm, b=1.509 7(6) nm, c=1.683 2(6) nm, β=115.231(14)°, Z=4, μ=4.311 mm-1, final R1=0.020 9, wR2=0.045 4. CCDC: 272214.