SYNTHESIS,CHARACTERIZATION,THERMAL DEGRADATION AND ELECTRICAL CONDUCTIVITY OF OLIGO[2-(THIEN-2-YLMETHYLENE)AMINOPHENOL]AND OLIGOMER-METAL COMPLEXES

作     者：smet Kaya Aysel Aydin 

作者机构：Department of ChemistryFaculty of Science and ArtsCanakkale Onsekiz Mart UniversityTR-17020CanakkaleTurkey 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2009年第27卷第4期

页      面：465-477页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 0817[工学-化学工程与技术] 08[工学] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：supported by the Government Planning Organization(GPO2002K120170-7) TUBITAK GrantsCommission for a research grant(No.TBAG-105T428) 

主　　题：Air O_2 NaOCl O1igo[2-(thien-2-yl-methylene)aminophenol] Oxidative polycondensation Thermal analysis Electrical conductivity Oligomer-metal complex compounds 

摘      要：The optimum reaction conditions of the oxidative polycondensation of 2-(thien-2-yl-methylene)aminophenol (2-TMAP) has been accomplished by using air O_2,H_2O_2 and NaOCl oxidants in an aqueous alkaline medium between 20℃and 90℃.The structures of the monomer and oligomer were confirmed by FT-IR,UV-Vis,~1H-NMR and ^(13)C-NMR and elemental ***-DTA,size exclusion chromatography(SEC) techniques and solubility tests were applied for *** ~1H-NMR and ^(13)C-NMR data show that the polymeriz...