Enhanced green emission from La＿(0.4)F＿3:Ce＿(0.45),Tb＿(0.15)/TiO＿2 core/shell structure

作     者：T.K.Srinivasan B.S.Panigrahi N.Suriyamurthy P.K.Parida B.Venkatraman 

作者机构：Indira Gandhi Centre for Atomic ResearchKalpakkam–603102 India 

出 版 物：《Journal of Rare Earths》 (稀土学报（英文版）)

年 卷 期：2015年第33卷第1期

页      面：20-26页

核心收录：

学科分类：0709[理学-地质学] 0819[工学-矿业工程] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0708[理学-地球物理学] 0703[理学-化学] 070301[理学-无机化学] 

主　　题：core-shell cerium terbium luminescence lanthanum fluoride scintillation rare earths 

摘      要：Nano sized La0.4F3：Ce0.45,Tb0.15（core）, La0.4F3：Ce0.45,Tb0.15（Ti O2）（core） shell, La0.55F：Ce0.45, and La0.85F3：Tb0.15 particles were synthesized by adopting co-precipitation technique in acidic environment and coated with Ti O2 to form a core-shell structure by adopting a mechanical dispersion method at room temperature. The synthesized materials were characterized using X-ray diffraction（XRD）, transmission electron microscopy（TEM）, Fourier transform infrared spectroscopy（FTIR）, ultraviolet-visible spectroscopy（UV-Vis） absorption, photoluminescence and lifetime spectroscopy. The crystal structure of La0.4F3：Ce0.45,Tb0.15 remained the same as La F3 after being doped with Ce and Tb ions but with a slight decrease in the lattice parameter. TEM image confirmed the formation of a core-shell structure. The La0.4F3：Ce0.45,Tb0.15/Ti O2 exhibited Tb3＋ fluorescence enhancement by a factor of 1.76. Scintillation from the synthesized materials was also observed under X-ray excitation.