Practical reduction of imines by NaBH_4/alumina under solvent-free conditions:An efficient route to secondary amine

作     者：Foad Kazemi Ali Reza Kiasat Ebrahim Sarvestani 

作者机构：Institute for Advanced Studies in Basic Sciences(IASBS)Zanjan 45195Iran Chemistry DepartmentCollege of ScienceShahid Chamran UniversityAhvaz 61357-4-3169Iran 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2008年第19卷第10期

页      面：1167-1170页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Chamran University Research Council are gratefully acknowledged 

主　　题：Imine Secondary amine Solvent free Reduction Sodium borohydride 

摘      要：Sodium borohydride supported on alumina reduces imines to the corresponding secondary amines in high to excellent isolated yields under solvent-free conditions. Noteworthy is that highly chemoselective reactions were achieved in the presence of other functional groups such as halogen, nitro, and cyano groups.