The adsorption isotherms, IR and ^(29)Si MAS NMR spectra of modified MCM-41 molecular sieves
The adsorption isotherms, IR and ^(29)Si MAS NMR spectra of modified MCM-41 molecular sieves作者机构:Department of Chemistry Fudan University Shanghai China Centre of Analysis and Measurement Fudan University Shanghai China
出 版 物:《Chinese Science Bulletin》 (中国科学通报)
年 卷 期:1997年第42卷第10期
页 面:828-832页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
基 金:Chinese Academy of Science
主 题:MCM-41 surface modification adsorption isotherm IR 29Si MAS NMR.
摘 要:RECENTLY a new family of mesoporous molecular sieves,M41S,was reported by researchers atMobil R&D *** a member of the family,MCM-41,which exhibits a hexagonalarray of uniform channel mesopores,has been *** channel size can be variedfrom approximately 1.5 nm to greater than 10 nm by choosing different surfactants,auxiliarychemicals(1,3,5-trimethylbenzene)in the reactant,and by changing the reaction *** wall thickness of this kind of molecular sieve is in the range of 0.3 to 1.3 nm esti-