Synthesis, characterization and electrical conductivity of poly [ethyl trifluorobuty-2-noate]

作     者：Yang, SY Zhao, WY Huang, YZ Zhang, XQ Zhang, JY 

作者机构：CHINESE ACAD SCISHANGHAI INST ORGAN CHEMSHANGHAI 200032PEOPLES R CHINA 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：1995年第13卷第6期

页      面：545-551页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：Project supported by the National Natural Science Foundation of China 

主　　题：fluoro-polyacetylene doping synthesis characterization electrical conductivity 

摘      要：Poly[ethyl trifluorobuty-2-noate] (PETFB) was prepared from ethyltrifluorobuty-2-noate by anionic polymerization. The polymer was examined by UV-Vis, IR and NMR spectrometries. It possessed pi-conjugated backbone in the main chain. No significant variation in the electrical conductivity of BF3-doped PETFB was observed after more than three months storage, indicating improved conductive stability in air as compared with polyacetylene.