Hydrogen Production by Chemical Looping Gasification of Corn Stalk Driven by a tert-Butanol Solution

作     者：QIN Wu CHEN Shubo ZHU Jinqi ZHANG Maodong XIAO Xianbin 

作者机构：National Engineering Laboratory for Biomass Power Generation EquipmentNorth China Electric Power UniversityBeijing 102206P.R.China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2019年第35卷第6期

页      面：1012-1017页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 08[工学] 0703[理学-化学] 

基　　金：Supported by the National Natural Science Foundation of China(No.51776071) the Fundamental Research Funds for the Central Universities of China(Nos.2018ZD08,2018MS034,2016YQ07) the National Key R&D Program of China(No.2016YFB0600205-04). 

主　　题：Chemical looping gasification Hydrogen energy Biomass Wastewater,Oxygen carrier 

摘      要：The purpose of this work is to convert organic wastewater into oxidants(H2O and CO2)to promote biomass gasification during the chemical looping process to achieve high-H2/CO-ratio syngas.A tert-butanol solution was selected as the model organic wastewater to generate enough H2O and CO2 to promote corn stalk chemical looping gasification(CLG).A series of CLG experiments was conducted at 850℃ under various degrees of oxygen excess(Ω).AnΩof approximately 0.9 led to the highest hydrogen yield and fixed carbon conversion compared with the other cases.Chemometrics and thermodynamic analysis further validated the possibility of corn stalk CLG using a tert-butanol solution.The results show that CLG of biomass-organic wastewater can both treat organic waste and promote chemical looping processes.