Magnetic and XPS studies of lithium lanthanide tetraphosphates LiLnP_4O_(12)(Ln=Nd,Gd,Er)

作     者：D.Petrov B.Angelov V.Lovchinov 

作者机构：Department of Physical Chemistry Plovdiv University"Paisii Hilendarski" 24 Tsar Asen Str. 4000 Plovdiv Bulgaria Department of Inorganic and Physical ChemistryUniversity of Food Technologies-Plovdiv26 Maritsa Blvd. 4002 Plovdiv Bulgaria Institute of Solid State PhysicsBulgarian Academy of Sciences72Tsarigradsko Chaussee Blvd.1784 SofiaBulgaria 

出 版 物：《Journal of Rare Earths》 (稀土学报（英文版）)

年 卷 期：2013年第31卷第5期

页      面：485-489页

核心收录：

学科分类：07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学] 

基　　金：supported by National Science Fund(DO-02-352) 

主　　题：lithium lanthanide tetraphosphates single crystals magnetic properties XPS spectroscopy rare earths 

摘      要：Magnetic susceptibilities of flux-grown single crystals of LitnP4012 （Ln=Nd, Gd, Er） were measured in the temperature range of 2-300 K. The compounds were paramagnetic, and obeyed the Curie-Weiss law in the entire temperature interval, without magnetic phase transitions, and with effective magnetic moments close to those of the corresponding free Ln3＋ ions. X-ray photoelec- tron spectroscopy was applied to determine the positions of core-level electrons relative to the Fermi level： Li is; Ln 4f, 5p, 5s, 4d, 3d; P 2s, 2p; O 1s, 2s. The binding energies in these compounds were found slightly shifted compared to the respective values of the same elements.