Solvent- and Catalyst-Free Microwave-Assisted Decarboxylation of Malonic Acid Derivatives

作     者：Fanny Araceli Cabrera-Rivera Luis Gabriel Hernández-Vázquez Patricia Flores-Sánchez Maria Durán-Galván Jaime Escalante 

作者机构：The Center of Chemical Research UAEM Cuernavaca México SIGNA Civac S. A. de C. V. Jiutepec México 

出 版 物：《Green and Sustainable Chemistry》 (绿色与可持续化学（英文）)

年 卷 期：2017年第7卷第4期

页      面：270-280页

学科分类：07[理学] 0703[理学-化学] 

主　　题：Microwave Decarboxylation Malonic Acid Derivatives Solvent-Free Catalyst-Free Green Chemistry 

摘      要：It has been found that microwave assisted decarboxylation of malonic acid derivatives can be achieved under solvent-free and catalyst free conditions. This new method produces the corresponding carboxylic acid in a pure manner and with a high yield in a very short reaction time: 3 - 10 min. In general terms, the condition under which this reaction is carried out accelerates the decarboxylation significantly of a series of disubstituted malonic acid derivatives, and makes this new process efficient, easy and environmentally friendly.