Recent advances in sulfenylation of C(sp^3)-H bond under transition metal-free conditions

作     者：Xin-Ming Xu De-Mao Chen Zu-Li Wang Xin-Ming Xu;De-Mao Chen;Zu-Li Wang

作者机构：College of Chemistry and Chemical EngineeringYantai UniversityYantai 264005China College of Chemistry and Pharmaceutical SciencesQingdao Agricultural UniversityQingdao 266109China School of Chemistry and Chemical EngineeringHunan University of Science and TechnologyXiangtan 411201China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2020年第31卷第1期

页      面：49-57页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：financial support from the Young Scholars Research Fund of Yantai University (No.HY19B06) 

主　　题：Sulfenylation C(sp^3)-H bond Metal-free Reaction mechanism Synthetic method 

摘      要：In recent years,the transition metal-free sulfenylation of C-H bond for C-S formation has been rapidly advanced and has become an eco-friendly synthetic tool for pharmacists and organic *** natural or bioactive molecules such as(hetero)arenes,olefins,carbonyl compounds,alkanes,have been employed for sulfenylating *** review will focus on the recent five-year advances in C-S bond formation via direct sulfenylation of C(sp^3)-H bonds under metal-free conditions and elaborate their mechanisms from a new perspective.