Dendronized Polymers with High FTC-chromophore Loading Density:Large Second-order Nonlinear Optical Effects, Good Temporal and Thermal Stability

作     者：Meng Jin Zhao-Chen Zhu Qiu-Yan Liao Qian-Qian Li Zhen Li Meng Jin;Zhao-Chen Zhu;Qiu-Yan Liao;Qian-Qian Li;Zhen Li

作者机构：Department of ChemistrySauvage Center for Molecular SciencesWuhan UniversityWuhan 430072China Institute of Molecular Aggregation ScienceTianjin UniversityTianjin 300072China 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2020年第38卷第2期

页      面：118-125,I0005页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：financially supported by the National Natural Science Foundation of China (No. 21734007) 

主　　题：Second-order nonlinear optics Dendronized polymers Chromophore 

摘      要：In this study,two new dendronized nonlinear optical(NLO)polymers were synthesized with high FTC chromophore loading density by introduction of high generation chromophore dendrons on the side *** to their suitable molecular weights,both of them possessed good solubility in common *** also inherited the advantages of dendrimers(large NLO coefficient),especially for PG2 whose NLO coefficient d33 value was as high as 282 pm·V^–***,PG2 had a good temporal stability with 80%of its maximum value being retained at the temperature as high as 129℃.