Removal and transformation of organic matter during soil-aquifer treatment

作     者：ZHAO Qing-liang XUE Shuang YOU Shi-jie WANG Li-na 

作者机构：School of Municipal ＆ Environmental Engineering Harbin Institute of Technology Harbin 150090 China 

出 版 物：《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 (浙江大学学报（英文版）A辑（应用物理与工程）)

年 卷 期：2007年第8卷第5期

页      面：712-718页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 08[工学] 

基　　金：Project (No. 2004CB418505) supported by the National Basic Research Program (973) of China 

主　　题：Soil-aquifer treatment (SAT) Organic matter Dissolved organic matter Trihalomethane formation potential Bio-degradable dissolved organic carbon (BDOC) Specific trihalomethane formation potential 

摘      要：This study investigated the removal and transformation of organic matter through laboratory-scale soil-aquifer treatment (SAT) soil columns over a 110-day period. Reductions in total organic carbon (TOC), dissolved organic carbon (DOC), biodegradable dissolved organic carbon (BDOC), nonbiodegradable dissolved organic carbon (NBDOC) and absorbance of ul-traviolet light at 254 nm (UV-254) averaged 71.46%, 68.05%, 99.31%, 33.27% and 38.96% across the soil columns, respectively. DOC/TOC ratios increased slightly with depth while BDOC/DOC ratios showed a converse trend. DOC exiting the soil-column system contained only a very small biodegradable fraction. SAT decreased the concentration of DOC present in feed water but increased its aromaticity, as indicated by specific ultraviolet light absorbance (SUVA), which increased by 50%～115% across the soil columns, indicating preferential removal of non-aromatic DOC during SAT. Overall, laboratory-scale SAT reduced triha-lomethane formation potential (THMFP), although specific THMFP increased. THMFP reduction was dominated by removal in chloroform. All samples exhibited a common general relationship with respect to weight: chloroformdichlorobromomethane dibromochloromethanebromoform.