Synthesis of Poly(styrene-b-isoprene-b-styrene)viaNitroxide-mediated Radical Polymerization by a Novel Alkoxyamine

作     者：GAO Long-cheng PAN Qi-wei FAN Xing-he CHEN Xiao-fang WAN Xin-hua ZHOU Qi-feng 

作者机构：College of Chemistry and Molecular Engineering Peking University Beijing 100871 P. R. China Key Laboratory of Polymer Chemistry and Physics of Ministry of Education Bering 100871 P. R. China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2005年第21卷第5期

页      面：615-618页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：Supported by the National Natural Science Foundation of China(No. 20134010) the Science Research Fund of the Minis-try of Education of P. R. China(No. 104005) 

主　　题：Radical polymerization Block copolymer Nitroxide Isoprene 

摘      要：Bifunctional alkoxyamine bis-TIPNO derived from 2,2,5-trimethyl-4-phenyl-3-azahexane-3-oxyl （TIPNO） and α, ω-alkyl bromide by atom transfer radical addition（ATRA） was employed as “biradical initiator for nitroxide-mediated radical polymerization（NMRP） of isoprene and styrene. The kinetics study for the polymerization of styrene at different time showed living features. The poly（styrene-b-isoprene-b-styrene） （SIS） copolymers have two glass transition temperatures, indicating the immiscibility of the corresponding blocks.