In(OTf)_3 catalyzed allylation reaction of imines with tetraallyltin

作     者：Xiao Ning Wei Ling Yan Liu Bing Wang Wei Xing Chang Jing Li 

作者机构：The State Key Laboratory Elemento-Organic Chemistry Institute of Elemento-Organic Chemistry Nankai University Tanjin 300071 China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2009年第20卷第1期

页      面：40-43页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：the National Natural Science Foundation of China(Nos.20421202 20372033)for financialsupport 

主　　题：Catalytic allylation Aldimine Tetraallyltin In(OTf)3 

摘      要：In the presence of catalytic amount of In（OTf）3 （10 mol%）, a series of aldimines reacted with tetraallyltin in a 2：1 molar ratio to afford the corresponding homoallylic amines in good yields. The good atom efficiency was achieved under mild reaction conditions and a new protocol （allyl）4Sn/In（OTf）3 for simple imines was developed.