Cooperative effects at the interface of nanocrystalline metal-organic frameworks

作     者：Bunyarat Rungtaweevoranit Yingbo Zhao Kyung Min Choi Omar M. Yaghi 

作者机构：Department of ChemistryUniversity of California-BerkeleyMaterials Sciences DivisionLawrence Berkeley National LaboratoryKavli Energy NanoSciences Institute at BerkeleyBerkeleyCalifornia 94720USA 

出 版 物：《Nano Research》 (纳米研究（英文版）)

年 卷 期：2016年第9卷第1期

页      面：47-58页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 080202[工学-机械电子工程] 08[工学] 0817[工学-化学工程与技术] 0804[工学-仪器科学与技术] 0802[工学-机械工程] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：supported by the Royal Thai Government Scholarship. Research in the Yaghi group on nanoMOFs is supported by BASF (Ludwigshafen, Germany) U.S. Department of Defense, Defense Threat Reduction Agency 

主　　题：metal--organic framework inorganic nanocrystal cooperative effects interface design 

摘      要：Controlling the chemistry at the interface of nanocrystalline solids has been a challenge and an important goal to realize desired properties. Integrating two different types of materials has the potential to yield new functions resulting from cooperative effects between the two constituents. Metal-organic frameworks （MOFs） are unique in that they are constructed by linking inorganic units with organic linkers where the building units can be varied nearly at will. This flexibility has made MOFs ideal materials for the design of functional entities at interfaces and hence allowing control of properties. This review highlights the strategies employed to access synergistic functionality at the interface of nanocrystalline MOFs （nMOFs） and inorganic nanocrystals （NCs）.