Catalysts for Hydration of Cyclohexene to Cyclohexanol
Catalysts for Hydration of Cyclohexene to Cyclohexanol作者机构：Shandong Provincial Key Lab of Chemical Engineering Institute of Applied Catalysis Yantai University Yantai 264005 P. R. China
出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)
年 卷 期：2013年第29卷第4期
页 面：743-746页
核心收录：
学科分类：081702[工学-化学工艺] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术]
基 金：Supported by the Science and Technology Development Project of Shandong Province China
主 题：Hydration Cyclohexene Ion-exchange resin Modification Aminate rate
摘 要：The hydration of cyclohexene was determined in a stirred tank of 100 mL in a batch mode in the presence of modified or unmodified resin as catalyst. The ion-exchange sulfonate resin was modified with alkyl secondary amine. At an optimum amination rate of 15%, the conversion of cyclohexene reached to 22% and the selectivity of cyclohexanol was 95.6%. In a temperature range of 90--150℃, the activity and selectivity of the modified resin ca- talyst were much higher than those of the unmodified resin catalyst, which was attributed to the inclusion formed between cyclohexene and alkyl chain and also the quasi-lipophilic phase formed around the outer surface of resin beads. The formed quasi-lipophilic phase formed enhanced the conversion of cyclohexene and depressed the forma- tion of by-products.
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