In situ electron-induced reduction of NOx via CNTs activated by DBD at low temperature
作者机构：Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention(LAP3)Institute of Environmental ScienceFudan UniversityShanghai 200433China National Engineering Laboratory for VOCs Pollution Control Material&TechnologyUniversity of Chinese Academy of SciencesBeijing 100049China Shanghai Institute for Design&Research on Environmental EngineeringShanghai 200232China
出 版 物：《Frontiers of Environmental Science & Engineering》 (环境科学与工程前沿（英文）)
年 卷 期：2020年第14卷第2期
页 面：87-96页
核心收录：
学科分类：0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081704[工学-应用化学] 07[理学] 070205[理学-凝聚态物理] 08[工学] 070304[理学-物理化学(含∶化学物理)] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学]
基 金：the National Natural Science Foundation of China(No.21577023) the National Key Research and Development Program of China(No.2017YFC0212900) the Special Research Project on Causes and Control Technology of Air Pollution(No.2017YFC0212905) the Science and Technology Innovation Action Project supported by the Science and Technology Commission of Shanghai Municipality(No.18DZ1202605)
主 题：Dielectric barrier discharge NOx abatement In situ electron-induced reduction Carbon nanotubes
摘 要：In this study,a new in situ electron-induced process is presented with carbon nanotubes(CNTs)as a reduction agent activated by dielectric barrier discharge(DBD)for nitrogen oxide(NOx)abatement at low temperature(407 K).Compared with a single DBD system and a DBD system with activated carbon(DBD-AC),a DBD system with carbon nanotubes(DBD-CNT)showed a significant promotion of NOx removal efficiency and N2 *** the 02 content was 10%,the NOv conversion and N2 selectivity in the DBD-CNT system still reached 64.9%and 81.9%at a specific input energy(SIE)of 1424 J^L,and these values decreased to 16.8%,31.9%and 43.2%,62.3%in the single DBD system and the DBD-AC system,respectively.X-ray photoelectron spectroscopy(XPS)and scanning electron microscopy(SEM)were utilized to investigate surface changes in the CNTs after activation by DBD to explore the NO.t reduction abatement mechanism of this new ***,the outlet gas components were also observed via Fourier transform infrared spectroscopy(FTIR)to help reveal the NOr reduction *** results verified that carbon atoms excited by DBD and the structure of CNTs contributed to the synergistic activity of the DBD-CNT *** new deNOx process was accomplished through in situ heterogenetic reduction reactions between the NOx and carbon atoms activated by the plasma on the *** addition,further results indicated that the new deNOv process exhibited acceptable S02 tolerance and water resistance.
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