Carbon-Carbon Bond Formation Reactions in the Preparation of Hydrindanones
Carbon-Carbon Bond Formation Reactions in the Preparation of Hydrindanones作者机构:Faculty of Pharmaceutical Sciences Tokushima Bunri University Yamashiro-cho Tokushima 770-8514 Japan Present address. Colleage of Pharmaceutical Scienoes Zhejiang University of Technology Hangzhou 310014 China.
出 版 物:《复旦学报(自然科学版)》 (Journal of Fudan University:Natural Science)
年 卷 期:2005年第44卷第5期
页 面:811-812页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
摘 要:Carbon-carbon bond formation reactions are highly important in organic chemistry, because these reactions may be used to construct complicated molecules. Samarium diiodide is known to be a one-electron reducing agent and recently used in many organic reactions. A radicals is postulated as an intermediate, which may be formed by direct reduction of halides, carbonyls and other functional groups.