A Facile and Efficient Synthesis of N,N-Dimethylarylamines from Aryl Bromides

作     者：Jian Kui ZHAO Yan Guang WANG 

作者机构：Department of ChemistryZhejiang UniversityHangzhou 310027 

出 版 物：《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期：2002年第13卷第12期

页      面：1149-1151页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：Amination nickel-catalyzed cross-coupling reaction N, N-dimethylarylamine. 

摘      要：Catalytic amination of aryl bromides with in situ generated dimethylamines from N, N- dimethylacetamide (DMA) has been successfully carried out using Ni(Phen)Cl2 as catalyst. Both electron-rich and electron-poor aromatic system reacted smoothly under the conditions to give N,N-dimethylarylamines in good yields.