Enhanced desulfurization performance of hybrid membranes using embedded hierarchical porous SBA-15

作     者：Ye Zhang Jian Song Josue Quispe Mayta Fusheng Pan Xue Ga Mei Li Yimeng Song Meidi Wang Xingzhong Cao Zhongyi Jiang Ye Zhang;Jian Song;Josue Quispe Mayta;Fusheng Pan;Xue Gao;Mei Li;Yimeng Song;Meidi Wang;Xingzhong Cao;Zhongyi Jiang

作者机构：School of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072China Collaborative Innovation Center of Chemical Science and Engineering(Tianjin)Tianjin 300072China Multi-discipline Research DivisionInstitute of High Energy PhysicsChinese Academy of SciencesBejing 100049China 

出 版 物：《Frontiers of Chemical Science and Engineering》 (化学科学与工程前沿（英文版）)

年 卷 期：2020年第14卷第4期

页      面：661-672页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(Grant Nos.21621004,21409583,and 21878216) the Program of Introducing Talents of Discipline to Universitics(No.B06006) the State Key Laboratory of Organic-Inorganic Composites(No.0IC-201801003) the Open Projec Program of State Key Laboratory of Petroleum Pollution Control(Grant No.PPC2017014) CNPC Research Institute of Safety and Environmental Technology 

主　　题：hybrid membranes hierarchical porous SBA-15 sieving effect pervaporation desulfurization 

摘      要：The utilization of materials with a hierarchical porous structure as multi-functional additives is highly attractive in the preparation of hybrid *** this study,novel hybrid membranes are designed by embed-ding hierarchical porous Santa Barbara Amorphous 15(SBA-15)with a dual-pore architecture(micropores and mesopores)for pervaporation *** SBA-15 with cylindrical mesopores provides molecular transport expressways to ensure improved permeability,while micropores on the wall have molecular sieving effects that are essential for the enhancement of permselectivity of thiophene *** thiophene/n-octane mixture as a model system,the hybrid membrane with embedded 6 wt-%SBA-15 exhibits optimal pervaporation desulfurization performance with a permeation flux of 22.07 kg·m^-2·h^-1 and an enrichment factor of ***,the detailed structure and properties of hybrid membranes are systematically *** study demonstrates the immense potential of hierarchical porous materials as additives in membranes to simultaneously increase permeability and permselectivity.