Simulating the transfer and fate of hexachlorocyclohexane in recent 50 years in Beijing, China

作     者：CAO Hongying1, LIANG Tao1 & TAO Shu2 1. Institute of Geographical Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing 100101, China 2. Laboratory for Earth Surface Processes, Peking University, Beijing 100871, China 

作者机构：Institute of Geographical Sciences and Natural Resources Research Chinese Academy of Sciences Beijing China Laboratory for Earth Surface Processes Peking University Beijing China 

出 版 物：《Science China Earth Sciences》 (中国科学（地球科学英文版）)

年 卷 期：2005年第48卷第12期

页      面：2203-2213页

核心收录：

学科分类：082803[工学-农业生物环境与能源工程] 08[工学] 0828[工学-农业工程] 0708[理学-地球物理学] 0704[理学-天文学] 

基　　金：This work was supported by the Knowledge Innovation Project of Chinese Academy of Sciences(Grant No.KZCX3-SW-429) the National Science Foundation of China(Grant No.40332015) China Postdoctoral Science Foundation(Grant No.2004035411) 

主　　题：fugacity model, hexachlorocyclohexane, compartment, transfer flux, fate. 

摘      要：Taking Beijing as a study area, a dynamic fugacity model was used to simulate the transfer and fate of technical HCHs according to the physic-chemical properties of the studying environment and HCH isomers. Dynamic changes of the transfer fluxes and concentrations of HCH isomers during 1952―2003 were simulated and the model results suggest good agreement between the calculated and measured concentrations of HCH isomers. During 1952―1983, the average input and output amount of HCHs through agricultural application and degradation are 130 t and 150 t respectively. The dominant transfer processes of HCHs in the study area are air-soil deposition, soil erosion and soil-air diffusion, transfer fluxes of these processes are 80 t?a?1, 16 t?a?1 and 11 t?a?1, which account for 92% of total transfer fluxes of HCHs isomers. There were approximately 253t HCHs in all environmental compartments of the study area during this period and 97% of which existed in soil compartment. Air and water advection became the dominant input sources of HCHs after 1984 when the application of technical HCHs was prohib-ited, concentration of HCHs quickly descended to a quite low level in several years. Total amount of HCHs isomers remaining in the study area environment now is less than 5% that before 1983, and this percentage may descend to 0.5% after 20 years by prediction.