Beyond graphene oxides: Emerging 2D molecular sieve membranes for efficient separation☆

作     者：Yi Liu 

作者机构：State Key Laboratory of Fine Chemicals Dalian University of Technology 

出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报（英文版）)

年 卷 期：2019年第27卷第6期

页      面：1257-1271页

核心收录：

学科分类：0710[理学-生物学] 080706[工学-化工过程机械] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 08[工学] 0817[工学-化学工程与技术] 0807[工学-动力工程及工程热物理] 0703[理学-化学] 

基　　金：Supported by the National Natural Science Foundation of China(21176231) the Fundamental Research Funds for the Central Universities(DUT16RC(3)103) Thousand Youth Talents Program 

主　　题：Two-dimentional material Molecular sieves Membranes Separation Desalination 

摘      要：Recent decades witnessed the significant progress made in the research field of 2D molecular sieve membranes.In comparison with their 3D counterparts, 2D molecular sieve membranes possessed several unique advantages like significantly reduced membrane thickness(one atom thick in theory) and diversified molecular sieving mechanisms(in-plane pores within nanosheets & interlayer galleries between nanosheets). M. Tsapatsis first carried out pioneering work on fabrication of lamellar ZSM-5 membrane. Since then, diverse 2D materials typically including graphene oxides(GOs) have been fabricated into membranes showing promising prospects in energy-efficient gas separation, pervaporation, desalination and nanofiltration. In addition to GOs, other emerging 2D materials, including 2D zeolites, 2D metal–organic frameworks(MOFs), 2 D covalent-organic frameworks(COFs), layered double hydroxides(LDHs), transition metal dichalcogenides(TMDCs), MXenes(typically Ti3C2TX), graphitic carbon nitrides(typically g-C3N4), hexagonal boron nitride(h-BN) and montmorillonites(MT) are showing intriguing performance in membrane-based separation process. This article summarized the most recent developments in the field of 2D molecular sieve membranes aside from GOs with particular emphasis on their structure–performance relationship and application prospects in industrial separation.