Diastereoselective Synthesis of 1,10-Dihydropyrrolo [ 1,2-a] [1,10]phenanthroline Derivatives via 1,3-Dipolar Cycloaddition Reaction

作     者：LIU Zhen-ming FANG Jun YAN Chao-guo 

作者机构：Analysis and Test CenterYangzhou University Yangzhou 225002 P.R.China College of Chemistry & Chemical EngineeringYangzhou University Yangzhou 225002 P.R.China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2013年第29卷第6期

页      面：1089-1093页

核心收录：

学科分类：081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 09[农学] 0904[农学-植物保护] 

基　　金：the National Natural Science Foundation of China the Priority Academic Program Development of Jiangsu Higher Education Institutions China 

主　　题：Pyridinium ylide Phenanthroline Pyrrolo[1,2-a]phenanthroline 1,3-Dipolar cycloaddition Diastereoselectivity 

摘      要：The functionalized 1,10-dihydropyrrolo[1,2-a][1,10]phenanthroline derivatives were synthesized in good yields and with high diastereoselectivity by 1,3-dipolar cycloaddition reactions of N-phenacylphenanthrolinium bromides or N-ethoxycarbonylmethylene phenanthrolinium bromide with various nitrostyrenes in acetonitrile at room temperature in the presence of triethvlamine,