Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly:Heading towards Framework Materials Synthesis over All Length Scales
Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly:Heading towards Framework Materials Synthesis over All Length Scales作者机构:College of Polymer Science and Engineering Sichuan University
出 版 物:《Chinese Journal of Polymer Science》 (高分子科学(英文版))
年 卷 期:2019年第37卷第11期
页 面:1045-1052页
核心收录:
主 题:Covalent organic framework (COF) Aerogel Framework crystallization
摘 要:Here, through the synergism between kinetic dynamic imine-exchange control and thermodynamic control, rarely observed compressible, porous, crystalline covalent organic framework (COF) aerogels were synthesized, the mechanism behind which is a framework crystallization induced self-assembly (FCISA) process. The prepared COF aerogel possessed extremely high BET surface over 2000 m^2·g^-1 and high maximum equilibrium adsorption capacity toward bisphenol-A of 699 mg·g^-1 in aqueous solution.