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Structural Features of(Ce,La or Sr)(Mn or Co)O_3 NanoPerovskites as a Catalyst for Carbon Monoxide Oxidation

Structural Features of (Ce,La or Sr)(Mn or Co)O_3 NanoPerovskites as a Catalyst for Carbon Monoxide Oxidation

作     者:Mahnaz Ghiasi Azim Malekzadeh 

作者机构:School of ChemistryDamghan University 

出 版 物:《Acta Metallurgica Sinica(English Letters)》 (金属学报(英文版))

年 卷 期:2014年第27卷第4期

页      面:635-641页

核心收录:

学科分类:081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

主  题:Carbon monoxide Nano perovskite Oxidation Cerium Lanthanum Strontium 

摘      要:The collection of different cations in the A and B sites of ABO3 was explored for the regularity of perovskites phase ***,Sr2?,La3?,and Ce4?are selected as the cations of site *** site B is considered to be Mn or Co *** analysis and Fourier transform infrared spectroscopy results confirm the formation of perovskite structure for catalysts in which La3?and Sr2?are considered as the cations of site *** is detected as the main crystalline phase when Ce4?is selected to be cation of site *** is found that the octahedral factor(rB/rO) takes the same important role as the tolerance factor to form cubic *** crystallite size of the products was calculated by data of the XRD and measured by the TEM *** of the XRD and TEM studies were supported by the study of the particles size distribution,which was carried out in a particle size *** perovskite samples were also used for stoichiometric oxidation of carbon monoxide with air.

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