Structural Features of(Ce,La or Sr)(Mn or Co)O_3 NanoPerovskites as a Catalyst for Carbon Monoxide Oxidation
Structural Features of (Ce,La or Sr)(Mn or Co)O_3 NanoPerovskites as a Catalyst for Carbon Monoxide Oxidation作者机构:School of ChemistryDamghan University
出 版 物:《Acta Metallurgica Sinica(English Letters)》 (金属学报(英文版))
年 卷 期:2014年第27卷第4期
页 面:635-641页
核心收录:
学科分类:081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术]
主 题:Carbon monoxide Nano perovskite Oxidation Cerium Lanthanum Strontium
摘 要:The collection of different cations in the A and B sites of ABO3 was explored for the regularity of perovskites phase ***,Sr2?,La3?,and Ce4?are selected as the cations of site *** site B is considered to be Mn or Co *** analysis and Fourier transform infrared spectroscopy results confirm the formation of perovskite structure for catalysts in which La3?and Sr2?are considered as the cations of site *** is detected as the main crystalline phase when Ce4?is selected to be cation of site *** is found that the octahedral factor(rB/rO) takes the same important role as the tolerance factor to form cubic *** crystallite size of the products was calculated by data of the XRD and measured by the TEM *** of the XRD and TEM studies were supported by the study of the particles size distribution,which was carried out in a particle size *** perovskite samples were also used for stoichiometric oxidation of carbon monoxide with air.